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Коллоидный журнал, 2023, T. 85, № 5, стр. 668-681

Ферментоподобная активность коллоидных растворов диоксида церия, стабилизированных L-яблочной кислотой

А. Д. Филиппова 1, А. Е. Баранчиков 1, *, В. К. Иванов 1

1 Институт общей и неорганической химии им. Н.С. Курнакова РАН
119991 Москва, Ленинский просп. 31, Россия

* E-mail: a.baranchikov@yandex.ru

Поступила в редакцию 29.06.2023
После доработки 26.07.2023
Принята к публикации 31.07.2023

Аннотация

Впервые получены устойчивые водные коллоидные растворы диоксида церия, стабилизированные L-яблочной кислотой, в мольных соотношениях лиганд : СеО2 = 0.2, 0.5, 1 и 2. С помощью метода динамического рассеяния света показано, что золи СеО2 характеризуются узким мономодальным распределением агрегатов по размерам и сохраняют агрегативную устойчивость в буферном растворе Tris-HCl. Хемилюминесцентный анализ ферментоподобной активности золей диоксида церия по отношению к пероксиду водорода показал, что модификация поверхности частиц диоксида церия яблочной кислотой приводит к увеличению их ферментоподобной активности до 4.5 раз.

Ключевые слова: нанозимы, пероксидазоподобная активность, золи, агрегаты

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