Геоэкология. Инженерная геология, гидрогеология, геокриология, 2023, № 5, стр. 65-78

Остатки от сжигания твердых коммунальных отходов: состав, выщелачивание загрязняющих веществ, обработка для уменьшения воздействия на окружающую среду

Т. И. Юганова 1*, В. С. Путилина 1**

1 Институт геоэкологии им. Е.М. Сергеева РАН
101000 Москва, Уланский пер., 13, стр. 2, Россия

* E-mail: tigryu@gmail.com
** E-mail: vputilina@yandex.ru

Поступила в редакцию 12.05.2023
После доработки 12.05.2023
Принята к публикации 16.05.2023

Аннотация

Сжигание – распространенный метод обработки твердых коммунальных отходов, позволяющий уменьшить их массу на 70% и объем до 90%. При этом большинство негорючих компонентов впоследствии концентрируется в относительно небольшом количестве остатков сжигания (ОСТКО) – шлаке и летучей золе, которые необходимо обрабатывать дополнительно и/или захоранивать на полигоне отходов. В статье описываются образование и состав ОСТКО, вопросы рециклинга и экологического регулирования, выщелачивание загрязняющих веществ и проблемы его тестирования, способы обработки ОСТКО для уменьшения воздействия на окружающую среду.

Ключевые слова: твердые коммунальные отходы, ТКО, остатки сжигания ТКО, шлак, летучая зола, тяжелые металлы, рециклинг, выщелачивание, тестирование выщелачивания, обработка остатков сжигания ТКО

Список литературы

  1. Yuganova T.I. [Methodology of the environmental life cycle assessment of municipal solid waste. Conceptual issues and examples of application]. Geoekologiya, 2020, no. 5, pp. 3–23. (in Russian)

  2. Blasenbauer D., Huber F., Lederer J., Quina M.J., Blanc-Biscarat D., et al. Legal situation and current practice of waste incineration bottom ash utilisation in Europ]. Waste Management, 2020, vol. 102, pp. 868–883.

  3. Di Gianfilippo M., Hyks J., Verginelli I., Costa G., et al. Leaching behaviour of incineration bottom ash in a reuse scenario: 12 years-field data vs. lab test result]. Waste Management, 2018, vol. 73, pp. 367–380.

  4. Dijkstra J.J., Meeussen J.C., van der Sloot H.A., Comans R.N. A consistent geochemical modelling approach for the leaching and reactive transport of major and trace elements in MSWI bottom ash. Applied Geochemistry, 2008, vol. 23, no. 6, pp. 1544–1562.

  5. Ecke H., Sakanakura H., Matsuto T., Tanaka N., Lagerkvist A. State-of-the-art treatment processes for municipal solid waste incineration residues inJapan. Waste Management & Research, 2000, vol. 18, no. 1, pp. 41–51.

  6. EN 12457-1:2002 – Characterisation of waste – Leaching – Compliance test for leaching of granular waste materials and sludges – Part 1: One stage batch test at a liquid to solid ratio of 2 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction). URL: https://www.en-standard.eu/une-en-12457-1-2003-characterisation-of-waste-leaching-compliance-test-for-leaching-of-granular-waste-materials-and-sludges-part-1-one-stage-batch-test-at-a-liquid-to-solid-ratio-of-2-l-kg-for-materials-with-high-solid-content-and-with-particle-size-below/ (accessed 26.03.2023)

  7. EN 12457-2:2002 – Characterisation of waste – Leaching; Compliance test for leaching of granular waste materials and sludges – Part 2: One stage batch test at a liquid to solid ratio of 10 l/kg for material with particle size below 4 mm (without or with size reduction). URL: https://ru.scribd.com/document/ 511437969/BS-EN-12457-2-2002 (accessed 26.03.2023)

  8. EN 12457-3:2002 – Characterization of waste – Leaching; Compliancetest for leaching of granular waste materials and sludges – Part 3: Two stagebatch test at a liquid to solid ratio of 2 l/kg and 8 l/kg for materials with highsolid content with particle size below 4 mm (without or with size reduction). URL: https://www.en-standard.eu/une-en-12457-3-2003-characterisation-of-waste-leaching-compliance-test-for-leaching-of-granular-waste-materials-and-sludges-part-3-two-stage-batch-test-at-a-liquid-to-solid-ratio-of-2-l-kg-and-8-l-kg-for-materials-with-high-solid-content-and-with-particle/ (accessed 26.03.2023)

  9. EN 12457-4:2002 – Characterisation of waste – Leaching – Compliance test for leaching of granular waste materials and sludges – Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with size reduction). URL: https://genorma.com/en/project/show/ cen:proj:14489 (accessed 26.03.2023)

  10. Haiying Z., Youcai Z., Jingyu Q. Characterization of heavy metals in fly ash from municipal solid waste incinerators in Shanghai. Process Safety & Environmental Protection, 2010, vol. 88, no. 2, pp. 114–124.

  11. Hykš J. Leaching from Municipal Solid Waste Incineration Residues: Ph. D. thesis / Technical University of Denmark, Department of Environmental Engineering, 2008, 64 p. https://www.osti.gov/etdeweb/servlets/purl/961973 (accessed 26.03.2023)

  12. Hyks J., Astrup T., Christensen T.H. Long-term leaching from MSWI air-pollution-control residues: Leaching characterization and modeling. Journal of Hazardous Materials, 2009, vol. 162, no. 1, pp. 80–91.

  13. Kylefors K., Andreas L., Lagerkvist A. A comparison of small-scale, pilot-scale and large-scale tests for predicting leaching behaviour of landfilled wastes. Waste Management, 2003, vol. 23, no. 1, pp. 45–59.

  14. Lam C.H.K., Ip A.W.M., Barford J.P., McKay G. Use of incineration MSW ash: A review. Sustainability, 2010, vol. 2, no. 7, pp. 1943–1968.

  15. Li W., Sun Y., Huang Y., Shimaoka T., Wang H., Wang Y., Ma L., Zhang D. Evaluation of chemical speciation and environmental risk levels of heavy metals during varied acid corrosion conditions for raw and solidified/stabilized MSWI fly ash. Waste Management, 2019, vol. 87, pp. 407–416.

  16. Lindberg D., Molin C., Hupa M. Thermal treatment of solid residues from WtE units: a review. Waste Management, 2015, vol. 37, pp. 82–94.

  17. Liu A., Ren F., Lin W.Y., Wang J.-Y. A review of municipal solid waste environmental standards with a focus on incinerator residues. International Journal of Sustainable Built Environment, 2015, vol. 4, no. 2, pp. 165–188.

  18. Luo H., Cheng Y., He D., Yang E.-H. Review of leaching behavior of municipal solid waste incineration (MSWI) ash. Science of the Total Environment, 2019, vol. 668, pp. 90–103.

  19. Management of APC Residues from W-t-E Plants. An overview of management options and treatment methods: Second edition / T. Astrup, Department of Environmental Engineering Technical University of Denmark; ISWA-WG Thermal Treatment of Waste, Subgroup APC Residues from W-t-E plants. ISWA, 2008. 51 pp. URL: https://books.google.se/books/about/ Management_of_APC_Residues_from_W_t_E_ Pl.html?id=WGh9XwAACAAJ&redir_esc=y (accessed 26.03.2023)

  20. Municipal solid waste incinerator residues / IAWG (International Ash Working Group: A.J. Chandler, T.T. Eighmy, O. Hartlén, D. Kosson, S.E. Sawell, H. van der Sloot, J. Vehlow), Amsterdam, Elsevier Science, 1997, 973 p. (Studies in Environmental Science. Vol. 67). URL: https://www.elsevier.com/books/municipal-solid-waste-incinerator-residues/chandler/ 978-0-444-82563-6 (accessed 18.04.2023)

  21. NEN 7375:2004 nl – Leaching characteristics – Determination of the leaching of inorganic components from moulded or monolitic materials with a diffusion test – Solid earthy and stony materials, The Netherlands. 39 pp. (in Dutch). URL: https://www.nen.nl/en/nen-7375-2004-nl-91729 (accessed 26.03.2023)

  22. Nikravan M., Ramezanianpour A.A., Maknoon R. Study on physiochemical properties and leaching behavior of residual ash fractions from a municipal solid waste incinerator (MSWI) plant. Journal of Environmental Management, 2020, vol. 260, article 110042.

  23. Quina M.J., Bordado J.C., Quinta-Ferreira R.M. Treatment and use of air pollution control residues from MSW incineration: An overview. Waste Management, 2008, vol. 28, no. 11, pp. 2097–2121.

  24. Sabbas T., Polettini A., Pomi R., Astrup T., Hjelmar O., et al. Management of municipal solid waste incineration residues. Waste Management, 2003, vol. 23, no. 1, pp. 61–88.

  25. Sakai S.-I., Hiraoka M. Municipal solid waste incinerator residue recycling by thermal processes. Waste Management. 2000, vol. 20, no. 2–3, pp. 249–258.

  26. Testing of Residues from Incineration of Municipal Solid Waste: Science report P1-494/SR2 / Environment Agency, UK, 2004, 126 p. https://assets.publishing.service.gov.uk/government/uploads/system/uploads/ attachment_data/file/290379/scho0105bijb-e-e.pdf (accessed 26.03.2023)

  27. Vehlow J., Bergfeldt B., Hunsinger H. PCDD/F and related compounds in solid residues from municipal solid waste incineration – a literature review. Waste Management & Research, 2006, vol. 24, no. 5, pp. 404–420.

  28. Weibel G., Eggenberger U., Schlumberger S., Mäder U.K. Chemical associations and mobilization of heavy metals in fly ash from municipal solid waste incineration. Waste Management, 2017, vol. 62, pp. 147–159.

  29. Wong S., Mah A.X.Y., Nordin A.H., Nyakuma B.B., Ngadi N., et al. Emerging trends in municipal solid waste incineration ashes research: a bibliometric analysis from 1994 to 2018. Environmental Science & Pollution Research, 2020, vol. 27, no. 8, pp. 7757–7784.

  30. Zhang H., He P.-J., Shao L.-M., Li X.-J. Leaching behavior of heavy metals from municipal solid waste incineration bottom ash and its geochemical modeling. Journal of Material Cycles & Waste Management, 2008, vol. 10, no. 1, pp. 7–13.

  31. Zhang Y., Cetin B., Likos W.J., Edil T.B. Impacts of pH on leaching potential of elements from MSW incineration fly ash. Fuel, 2016, vol. 184. pp. 815–825.

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